#------------------------------------------------------------------------------
#$Date: 2025-07-01 16:06:35 +0300 (Tue, 01 Jul 2025) $
#$Revision: 1360 $
#$URL: svn://crystallography.net/testcod/cif/4/30/00/4300047.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4300047
loop_
_publ_author_name
'Nalbandyan, Vladimir B.'
'Zvereva, Elena A.'
'Yalovega, Galina E.'
'Shukaev, Igor L.'
'Ryzhakova, Anastasiya P.'
'Guda, Alexander A.'
'Stroppa, Alessandro'
'Picozzi, Silvia'
'Vasiliev, Alexander N.'
'Whangbo, Myung-Hwan'
_publ_section_title
;
 Synthesis and Characterization of MnCrO4, a New Mixed-Valence
 Antiferromagnet
;
_journal_issue                   20
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              11850
_journal_page_last               11858
_journal_paper_doi               10.1021/ic401391b
_journal_volume                  52
_journal_year                    2013
_chemical_formula_sum            'Cr Mn O4'
_chemical_formula_weight         170.93
_space_group_IT_number           63
_space_group_name_Hall           '-C 2c 2'
_space_group_name_H-M_alt        'C m c m'
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_H-M   'C m c m'
_audit_creation_date             2013-04-13T17:57
_audit_creation_method           'from EXP file using GSAS2CIF'
_audit_update_record
;
2013-04-13T17:57  Initial CIF as created by GSAS2CIF

2013-05-29 # Formatted by publCIF
;
_cell_angle_alpha                90.0
_cell_angle_beta                 90.0
_cell_angle_gamma                90.0
_cell_formula_units_Z            4
_cell_length_a                   5.58762(16)
_cell_length_b                   8.45679(27)
_cell_length_c                   6.52132(23)
_cell_measurement_temperature    298
_cell_volume                     308.154(17)
_computing_structure_refinement  GSAS
_diffrn_ambient_temperature      298
_diffrn_measurement_device_type  ARL'Xtra
_diffrn_radiation_polarisn_ratio 0.803
_diffrn_radiation_probe          x-ray
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  1.00000
_exptl_absorpt_process_details
;   GSAS Absorption/surface roughness correction: function number 0
 No correction is applied.
;
_exptl_crystal_density_diffrn    3.685
_pd_block_id                     2013-04-13T17:57|MNCRO4_VAR8|mncro4_|
_pd_calc_method                  'Rietveld Refinement'
_pd_char_colour                  black
_pd_meas_2theta_range_inc        0.02
_pd_meas_2theta_range_max        99.96
_pd_meas_2theta_range_min        15.04
_pd_meas_number_of_points        4247
_pd_phase_name
'from E:/SHUKAEV/SCIENTIA/Str_An_2012/MnCrO4.VBN/VAR3/MnCrO4.cif'
_pd_proc_2theta_range_inc        0.02
_pd_proc_2theta_range_max        99.96452
_pd_proc_2theta_range_min        15.04452
_pd_proc_info_datetime           2013-04-13T17:57:26
_pd_proc_ls_background_function
;   GSAS Background function number 1 with 16 terms.
 Shifted Chebyshev function of 1st kind
      1:    62.0260     2:   -57.3275     3:    35.9441     4:   -25.8909    
      5:    21.2783     6:   -14.0700     7:    8.87208     8:   -8.34675    
      9:    6.09039    10:   0.141170    11:  -0.802661    12:   0.969665    
     13:  -0.607585    14:    2.09344    15:   -3.38773    16:    3.49820    
;
_pd_proc_ls_peak_cutoff          0.00100
_pd_proc_ls_pref_orient_corr
;   March-Dollase
 AXIS  1 Ratio=     2.207 Frac     0.028  h= 0.000  k= 0.000  l= 1.000
 AXIS  2 Ratio=     0.919 Frac     0.972  h= 1.000  k= 1.000  l= 0.000
 Prefered orientation correction range: Min=   0.85910, Max=   1.19625
;
_pd_proc_ls_profile_function
;
 CW Profile function number 3 with  19 terms
 Pseudovoigt profile coefficients as parameterized in
 P. Thompson, D.E. Cox & J.B. Hastings (1987). J. Appl. Cryst.,20,79-83.
 Asymmetry correction of L.W. Finger, D.E. Cox & A. P. Jephcoat (1994).
 J. Appl. Cryst.,27,892-900.
 #1(GU)   =    7.378 #2(GV)   =   29.882 #3(GW)   =    4.558
 #4(GP)   =    0.000 #5(LX)   =    7.337 #6(LY)   =   19.787
 #7(S/L)  =   0.0144 #8(H/L)  =   0.0141
 #9(trns) =     0.00 #10(shft)=   0.0000
 #11(stec)=     0.00 #12(ptec)=     0.00 #13(sfec)=     0.00
 #14(L11) =    0.000 #15(L22) =    0.000 #16(L33) =    0.000
 #17(L12) =    0.000 #18(L13) =    0.000 #19(L23) =    0.000
 Peak tails are ignored  where the intensity is below 0.0010 times the peak
   Aniso. broadening axis   0.0   0.0   1.0
;
_pd_proc_ls_prof_R_factor        0.0972
_pd_proc_ls_prof_wR_expected     0.1049
_pd_proc_ls_prof_wR_factor       0.1285
_pd_proc_number_of_points        4247
_refine_ls_goodness_of_fit_all   1.23
_refine_ls_matrix_type           full
_refine_ls_number_parameters     46
_refine_ls_number_restraints     0
_refine_ls_R_Fsqd_factor         0.10136
_refine_ls_shift/su_max          0.03
_refine_ls_shift/su_mean         0.01
_reflns_d_resolution_high        1.013
_reflns_d_resolution_low         4.662
_reflns_limit_h_max              5
_reflns_limit_h_min              0
_reflns_limit_k_max              8
_reflns_limit_k_min              0
_reflns_limit_l_max              6
_reflns_limit_l_min              0
_reflns_number_total             196
_cod_data_source_file            ic401391b_si_002.cif
_cod_data_source_block           MNCRO4_VAR8_publ
_cod_database_code               4300047
_gsas_exptl_extinct_corr_t_min   1.00000
_gsas_exptl_extinct_corr_t_max   1.00000
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +x,+y,+z
2 -x,+y,+z
3 +x,-y,+z+1/2
4 -x,-y,+z+1/2
-1 -x,-y,-z
-2 +x,-y,-z
-3 -x,+y,-z+1/2
-4 +x,+y,-z+1/2
101 +x+1/2,+y+1/2,+z
102 -x+1/2,+y+1/2,+z
103 +x+1/2,-y+1/2,+z+1/2
104 -x+1/2,-y+1/2,+z+1/2
-101 -x+1/2,-y+1/2,-z
-102 +x+1/2,-y+1/2,-z
-103 -x+1/2,+y+1/2,-z+1/2
-104 +x+1/2,+y+1/2,-z+1/2
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_thermal_displace_type
_atom_site_U_iso_or_equiv
_atom_site_symmetry_multiplicity
Mn Mn1 0.0 0.0 0.0 1.0 Uani 0.02699 4
Cr Cr1 0.0 0.36038(31) 0.25 1.0 Uani 0.02427 4
O O1 0.0 0.2474(6) 0.0414(8) 1.0 Uiso 0.0183(19) 8
O O2 0.2463(8) 0.4725(6) 0.25 1.0 Uiso 0.0162(18) 8
loop_
_atom_type_symbol
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_source
Mn 4.0 0.000 0.000 11.2819 5.34090 7.35730 0.34320 3.01930 17.8674 2.24410
83.7543 1.08960 International_Tables_Vol_C
Cr 4.0 0.000 0.000 10.6406 6.10380 7.35370 0.39200 3.32400 20.2626 1.49220
98.7399 1.18320 International_Tables_Vol_C
O 16.0 0.000 0.000 3.04850 13.2771 2.28680 5.70110 1.54630 0.32390 0.86700
32.9089 0.25080 International_Tables_Vol_C
loop_
_diffrn_radiation_wavelength
_diffrn_radiation_wavelength_wt
_diffrn_radiation_type
_diffrn_radiation_wavelength_id
1.540600 1.000 'Cu K\a~1~' 1
1.544400 0.500 'Cu K\a~2~' 2
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Mn1 O1 180.0 1_555 . -1_555 n
O1 Mn1 O2 90.57(18) 1_555 . 101_445 n
O1 Mn1 O2 90.57(18) 1_555 . 102_545 n
O1 Mn1 O2 89.43(18) 1_555 . 103_454 n
O1 Mn1 O2 89.43(18) 1_555 . 104_554 n
O1 Mn1 O2 89.43(18) -1_555 . 101_445 n
O1 Mn1 O2 89.43(18) -1_555 . 102_545 n
O1 Mn1 O2 90.57(18) -1_555 . 103_454 n
O1 Mn1 O2 90.57(18) -1_555 . 104_554 n
O2 Mn1 O2 81.45(18) 101_445 . 102_545 n
O2 Mn1 O2 98.55(18) 101_445 . 103_454 n
O2 Mn1 O2 180.0 101_445 . 104_554 n
O2 Mn1 O2 180.0 102_545 . 103_454 n
O2 Mn1 O2 98.55(18) 102_545 . 104_554 n
O2 Mn1 O2 81.45(18) 103_454 . 104_554 n
O1 Cr1 O1 109.8(4) 1_555 . -3_446 n
O1 Cr1 O2 109.04(12) 1_555 . 1_555 n
O1 Cr1 O2 109.04(12) 1_555 . 2_555 n
O1 Cr1 O2 109.04(12) -3_446 . 1_555 n
O1 Cr1 O2 109.04(12) -3_446 . 2_555 n
O2 Cr1 O2 110.9(4) 1_555 . 2_555 n
Mn1 O1 Cr1 132.45(31) 1_555 . 1_555 n
Mn1 O2 Mn1 97.23(18) 101_555 . 103_555 n
Mn1 O2 Cr1 126.72(15) 101_555 . 1_555 n
Mn1 O2 Cr1 126.72(15) 103_555 . 1_555 n
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Mn1 O1 2.109(5) . 1_555 n
Mn1 O1 2.109(5) . -1_555 n
Mn1 O2 2.1730(30) . 101_445 n
Mn1 O2 2.1730(30) . 102_545 n
Mn1 O2 2.1730(30) . 103_454 n
Mn1 O2 2.1730(30) . 104_554 n
Cr1 O1 1.662(5) . 1_555 n
Cr1 O1 1.662(5) . -3_555 n
Cr1 O2 1.671(5) . 1_555 n
Cr1 O2 1.671(5) . 2_555 n
O1 Mn1 2.109(5) . 1_555 n
O1 Cr1 1.662(5) . 1_555 n
O2 Mn1 2.1730(30) . 101_555 n
O2 Mn1 2.1730(30) . 103_555 n
O2 Cr1 1.671(5) . 1_555 n
loop_
_pd_meas_counts_total
_pd_proc_ls_weight
_pd_proc_intensity_bkg_calc
_pd_calc_intensity_total
272.0 0.00368 228.34557 228.32954
266.0 0.00376 228.26604 228.25035
236.0 0.00424 228.16267 228.14729
228.0 0.00439 228.03593 228.02087
257.0 0.00389 227.88638 227.87164
249.0 0.00402 227.71446 227.70003
228.0 0.00439 227.52069 227.50658
240.0 0.00417 227.30556 227.29176
216.0 0.00463 227.06952 227.05602
232.0 0.00431 226.81310 226.79990
244.0 0.00410 226.53667 226.52379
253.0 0.00395 226.24078 226.22820
237.0 0.00422 225.92584 225.91356
257.0 0.00389 225.59229 225.58031
244.0 0.00410 225.24060 225.22890
221.0 0.00452 224.87115 224.85976
260.0 0.00385 224.48445 224.47334
237.0 0.00422 224.08083 224.07001
239.0 0.00418 223.66078 223.65025
231.0 0.00433 223.22464 223.21439
236.0 0.00424 222.77290 222.76292
225.0 0.00444 222.30586 222.29616
235.0 0.00426 221.82401 221.81459
201.0 0.00498 221.32765 221.31850
234.0 0.00427 220.81721 220.80833
212.0 0.00472 220.29308 220.28447
211.0 0.00474 219.75555 219.74721
201.0 0.00498 219.20509 219.19701
218.0 0.00459 218.64197 218.63414
203.0 0.00493 218.06660 218.05904
187.0 0.00535 217.47929 217.47197
229.0 0.00437 216.88043 216.87337
222.0 0.00450 216.27028 216.26347
213.0 0.00469 215.64929 215.64273
230.0 0.00435 215.01765 215.01134
194.0 0.00515 214.37581 214.36974
200.0 0.00500 213.72400 213.71815
217.0 0.00461 213.06259 213.05699
177.0 0.00565 212.39182 212.38644
210.0 0.00476 211.71208 211.70694
196.0 0.00510 211.02362 211.01871
209.0 0.00478 210.32672 210.32204
195.0 0.00513 209.62169 209.61722
197.0 0.00508 208.90883 208.90457
214.0 0.00467 208.18837 208.18434
200.0 0.00500 207.46065 207.45683
182.0 0.00549 206.72589 206.72229
225.0 0.00444 205.98441 205.98100
184.0 0.00543 205.23640 205.23322
201.0 0.00498 204.48215 204.47916
192.0 0.00521 203.72195 203.71916
208.0 0.00481 202.95605 202.95346
194.0 0.00515 202.18463 202.18224
182.0 0.00549 201.40796 201.40575
224.0 0.00446 200.62631 200.62430
196.0 0.00510 199.83997 199.83812
169.0 0.00592 199.04897 199.04732
197.0 0.00508 198.25372 198.25224
182.0 0.00549 197.45435 197.45305
184.0 0.00543 196.65118 196.65005
176.0 0.00568 195.84427 195.84332
160.0 0.00625 195.03397 195.03319
192.0 0.00521 194.22037 194.21976
208.0 0.00481 193.40382 193.40338
175.0 0.00571 192.58440 192.58411
196.0 0.00510 191.76231 191.76218
199.0 0.00503 190.93776 190.93779
181.0 0.00552 190.11110 190.11128
185.0 0.00541 189.28223 189.28256
167.0 0.00599 188.45149 188.45198
179.0 0.00559 187.61906 187.61971
202.0 0.00495 186.78517 186.78593
169.0 0.00592 185.94983 185.95073
181.0 0.00552 185.11331 185.11435
197.0 0.00508 184.27576 184.27695
195.0 0.00513 183.43735 183.43867
157.0 0.00637 182.59834 182.59979
173.0 0.00578 181.75870 181.76028
174.0 0.00575 180.91866 180.92036
165.0 0.00606 180.07838 180.08022
176.0 0.00568 179.23811 179.24005
168.0 0.00595 178.39783 178.39989
173.0 0.00578 177.55769 177.55988
167.0 0.00599 176.71794 176.87605
170.0 0.00588 175.87874 176.03972
145.0 0.00690 175.04004 175.28105
169.0 0.00592 174.20209 174.44746
164.0 0.00610 173.36501 173.61488
155.0 0.00645 172.52901 172.78349
174.0 0.00575 171.69403 171.95322
169.0 0.00592 170.86031 171.12434
160.0 0.00625 170.02791 170.29694
174.0 0.00575 169.19707 169.47122
172.0 0.00581 168.36772 168.64714
167.0 0.00599 167.54008 167.82489
144.0 0.00694 166.71425 167.00461
165.0 0.00606 165.89038 166.18646
162.0 0.00617 165.06847 165.37044
160.0 0.00625 164.24863 164.55666
172.0 0.00581 163.43098 163.74527
172.0 0.00581 162.61569 162.93639
153.0 0.00654 161.80284 162.13016
171.0 0.00585 160.99240 161.32654
156.0 0.00641 160.18454 160.52571
171.0 0.00585 159.37933 159.72775
147.0 0.00680 158.57698 158.93286
136.0 0.00735 157.77734 158.14096
168.0 0.00595 156.98065 157.35225
159.0 0.00629 156.18694 156.56677
171.0 0.00585 155.39636 155.78468
173.0 0.00578 154.60887 155.00600
155.0 0.00645 153.82457 154.23079
162.0 0.00617 153.04353 153.45918
139.0 0.00719 152.26596 152.69133
151.0 0.00662 151.49174 151.92720
146.0 0.00685 150.72098 151.16690
139.0 0.00719 149.95378 150.41052
156.0 0.00641 149.19028 149.65823
164.0 0.00610 148.43034 148.90996
167.0 0.00599 147.67413 148.16583
159.0 0.00629 146.92174 147.42596
152.0 0.00658 146.17323 146.69049
136.0 0.00735 145.42854 145.95937
152.0 0.00658 144.68781 145.23268
142.0 0.00704 143.95107 144.51060
143.0 0.00699 143.21832 143.79312
173.0 0.00578 142.48976 143.08046
159.0 0.00629 141.76527 142.37250
153.0 0.00654 141.04494 141.66942
156.0 0.00641 140.32881 140.97131
147.0 0.00680 139.61700 140.27832
124.0 0.00806 138.90945 139.59042
152.0 0.00658 138.20619 138.90771
147.0 0.00680 137.50732 138.23032
141.0 0.00709 136.81290 137.55838
170.0 0.00588 136.12283 136.89188
121.0 0.00826 135.43724 136.23099
122.0 0.00820 134.75615 135.57581
137.0 0.00730 134.07962 134.92650
168.0 0.00595 133.40758 134.28305
140.0 0.00714 132.74014 133.64569
124.0 0.00806 132.07727 133.01448
137.0 0.00730 131.41910 132.38966
132.0 0.00758 130.76549 131.77122
146.0 0.00685 130.11658 131.15944
143.0 0.00699 129.47232 130.55443
131.0 0.00763 128.83282 129.95642
138.0 0.00725 128.19803 129.36555
135.0 0.00741 127.56793 128.78204
157.0 0.00637 126.94260 128.20613
150.0 0.00667 126.32206 127.63811
163.0 0.00613 125.70634 127.07826
146.0 0.00685 125.09535 126.52679
124.0 0.00806 124.48918 125.98409
145.0 0.00690 123.88781 125.45052
148.0 0.00676 123.29132 124.92657
121.0 0.00826 122.69959 124.41256
127.0 0.00787 122.11272 123.90909
154.0 0.00649 121.53069 123.41669
141.0 0.00709 120.95358 122.93611
129.0 0.00775 120.38126 122.46794
126.0 0.00794 119.81378 122.01304
139.0 0.00719 119.25117 121.57237
126.0 0.00794 118.69347 121.14703
119.0 0.00840 118.14060 120.73817
125.0 0.00800 117.59257 120.34719
108.0 0.00926 117.04939 119.97575
126.0 0.00794 116.51115 119.62579
150.0 0.00667 115.97770 119.29935
128.0 0.00781 115.44910 118.99905
146.0 0.00685 114.92537 118.72796
123.0 0.00813 114.40652 118.48958
116.0 0.00862 113.89244 118.28808
139.0 0.00719 113.38321 118.12858
147.0 0.00680 112.87881 118.01716
131.0 0.00763 112.37922 117.96115
106.0 0.00943 111.88449 117.96967
124.0 0.00806 111.39453 118.05366
125.0 0.00800 110.90933 118.22691
116.0 0.00862 110.42891 118.50667
134.0 0.00746 109.95332 118.91481
127.0 0.00787 109.48245 119.47916
129.0 0.00775 109.01630 120.48038
114.0 0.00877 108.55492 121.48182
136.0 0.00735 108.09828 122.90926
136.0 0.00735 107.64630 124.61652
107.0 0.00935 107.19901 126.86216
139.0 0.00719 106.75640 129.87238
162.0 0.00617 106.31850 134.02768
141.0 0.00709 105.88518 139.96629
146.0 0.00685 105.45650 148.70607
184.0 0.00543 105.03243 161.72801
201.0 0.00498 104.61298 180.92496
198.0 0.00505 104.19808 208.30234
213.0 0.00469 103.78774 245.28494
267.0 0.00375 103.38192 291.25928
341.0 0.002933 102.98068 340.73770
369.0 0.002710 102.58389 380.78262
383.0 0.002611 102.19157 396.64203
389.0 0.002571 101.80370 384.62201
336.0 0.002976 101.42030 351.37149
288.0 0.003472 101.04132 306.16983
257.0 0.00389 100.66671 259.44855
191.0 0.00524 100.29647 218.93346
161.0 0.00621 99.93057 187.39647
148.0 0.00676 99.56905 164.37952
149.0 0.00671 99.21178 148.18718
144.0 0.00694 98.85880 136.95038
130.0 0.00769 98.51007 129.08020
115.0 0.00870 98.16560 123.40589
98.0 0.01020 97.82531 119.14735
120.0 0.00833 97.48920 115.81893
123.0 0.00813 97.15723 113.12759
100.0 0.01000 96.82945 110.89473
131.0 0.00763 96.50574 109.00629
108.0 0.00926 96.18610 107.38508
110.0 0.00909 95.87051 105.97584
112.0 0.00893 95.55901 104.73756
90.0 0.01111 95.25146 103.63879
99.0 0.01010 94.94786 102.65529
96.0 0.01042 94.64825 101.76800
105.0 0.00952 94.35258 100.96175
135.0 0.00741 94.06075 100.22432
83.0 0.01205 93.77280 99.54591
95.0 0.01053 93.48870 98.91855
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35.0 0.02857 26.63672 37.24348
39.0 0.02564 26.60948 36.87815
34.0 0.02941 26.58185 36.50031
30.0 0.03333 26.55381 36.13581
24.0 0.0417 26.52539 35.80262
42.0 0.02381 26.49656 35.51151
37.0 0.02703 26.46736 35.26600
32.0 0.03125 26.43778 35.06293
32.0 0.03125 26.40783 34.89333
34.0 0.02941 26.37751 34.74330
35.0 0.02857 26.34683 34.59543
39.0 0.02564 26.31581 34.43123
26.0 0.0385 26.28443 34.23398
36.0 0.02778 26.25272 33.99175
29.0 0.03448 26.22067 33.69962
48.0 0.02083 26.18832 33.36011
23.0 0.0435 26.15565 32.98181
30.0 0.03333 26.12268 32.57725
33.0 0.03030 26.08942 32.16017
23.0 0.0435 26.05587 31.74345
31.0 0.03226 26.02205 31.33774
32.0 0.03125 25.98797 30.95098
33.0 0.03030 25.95365 30.58813
32.0 0.03125 25.91908 30.25205
25.0 0.0400 25.88429 29.94367
37.0 0.02703 25.84930 29.66237
36.0 0.02778 25.81409 29.40647
30.0 0.03333 25.77871 29.17345
32.0 0.03125 25.74314 28.96012
32.0 0.03125 25.70743 28.76303
24.0 0.0417 25.67157 28.57865
44.0 0.02273 25.63559 28.40394
31.0 0.03226 25.59949 28.23653
25.0 0.0400 25.56331 28.07505
30.0 0.03333 25.52705 27.91898
32.0 0.03125 25.49071 27.76840
30.0 0.03333 25.45435 27.62382
25.0 0.0400 25.41796 27.48573
26.0 0.0385 25.38157 27.35451
36.0 0.02778 25.34519 27.23033
25.0 0.0400 25.30886 27.11321
26.0 0.0385 25.27258 27.00294
39.0 0.02564 25.23637 26.89922
23.0 0.0435 25.20028 26.80174
28.0 0.0357 25.16429 26.71009
31.0 0.03226 25.12847 26.62392
22.0 0.0455 25.09281 26.54285
25.0 0.0400 25.05735 26.46658
33.0 0.03030 25.02211 26.39476
26.0 0.0385 24.98713 26.32711
23.0 0.0435 24.95242 26.26342
28.0 0.0357 24.91800 26.20344
16.0 0.0625 24.88392 26.14703
29.0 0.03448 24.85019 26.09406
24.0 0.0417 24.81686 26.04445
18.0 0.0556 24.78394 25.99813
41.0 0.02439 24.75148 25.95513
31.0 0.03226 24.71949 25.91546
30.0 0.03333 24.68802 25.87926
38.0 0.02632 24.65710 25.84665
26.0 0.0385 24.62676 25.81780
29.0 0.03448 24.59704 25.79297
22.0 0.0455 24.56796 25.77243
28.0 0.0357 24.53958 25.75650
26.0 0.0385 24.51191 25.73994
29.0 0.03448 24.48503 25.73438
21.0 0.0476 24.45894 25.73459
26.0 0.0385 24.43369 25.74100
26.0 0.0385 24.40933 25.75403
31.0 0.03226 24.38589 25.77411
25.0 0.0400 24.36342 25.80158
36.0 0.02778 24.34196 25.83669
33.0 0.03030 24.32157 25.87958
25.0 0.0400 24.30227 25.93011
24.0 0.0417 24.28412 25.98783
28.0 0.0357 24.26718 26.05177
29.0 0.03448 24.25147 26.12038
38.0 0.02632 24.23706 26.20267
22.0 0.0455 24.22399 26.27320
29.0 0.03448 24.21232 26.33701
34.0 0.02941 24.20210 26.39632
31.0 0.03226 24.19338 26.44563
30.0 0.03333 24.18622 26.48364
31.0 0.03226 24.18067 26.51092
22.0 0.0455 24.17679 26.52984
29.0 0.03448 24.17464 26.54420
29.0 0.03448 24.17428 26.55845
36.0 0.02778 24.17577 26.58060
27.0 0.0370 24.17916 26.60702
25.0 0.0400 24.18453 26.64396
27.0 0.0370 24.19194 26.69282
15.0 0.0667 24.20144 26.75369
27.0 0.0370 24.21312 26.82529
27.0 0.0370 24.22703 26.90496
21.0 0.0476 24.24325 26.98869
35.0 0.02857 24.26184 27.05270
14.0 0.0714 24.28288 27.12852
38.0 0.02632 24.30643 27.19127
29.0 0.03448 24.33259 27.23580
30.0 0.03333 24.36140 27.25048
22.0 0.0455 24.39297 27.25103
25.0 0.0400 24.42736 27.23117
33.0 0.03030 24.46466 27.19527
27.0 0.0370 24.50495 27.14921
29.0 0.03448 24.54829 27.09917
40.0 0.02500 24.59481 27.05275
37.0 0.02703 24.64454 27.01087
39.0 0.02564 24.69763 26.97871
29.0 0.03448 24.75410 26.94250
37.0 0.02703 24.81408 26.93435
25.0 0.0400 24.87768 26.92609
23.0 0.0435 24.94495 26.94087
28.0 0.0357 25.01603 26.96466
23.0 0.0435 25.09096 26.99515
18.0 0.0556 25.16990 27.02588
29.0 0.03448 25.25289 27.06286
30.0 0.03333 25.34007 27.09363
29.0 0.03448 25.43156 27.13120
29.0 0.03448 25.52741 27.16891
29.0 0.03448 25.62779 27.20802
29.0 0.03448 25.73274 27.25011
23.0 0.0435 25.84245 27.29708
29.0 0.03448 25.95694 27.35057
30.0 0.03333 26.07642 27.40424
30.0 0.03333 26.20092 27.47476
29.0 0.03448 26.33059 27.55498
31.0 0.03226 26.46561 27.64540
34.0 0.02941 26.60599 27.74612
26.0 0.0385 26.75197 27.85735
31.0 0.03226 26.90356 27.97899
40.0 0.02500 27.06101 28.11112
31.0 0.03226 27.22433 28.25014
21.0 0.0476 27.39376 28.40294
37.0 0.02703 27.56932 28.56592
38.0 0.02632 27.75120 28.73907
27.0 0.0370 27.93962 28.92243
32.0 0.03125 28.13457 29.11581
29.0 0.03448 28.33635 29.31934
33.0 0.03030 28.54494 29.53286
24.0 0.0417 28.76065 29.75645
28.0 0.0357 28.98347 29.98990
39.0 0.02564 29.21362 30.23317
19.0 0.0526 29.45136 30.48452
37.0 0.02703 29.69665 30.74664
39.0 0.02564 29.94985 31.01765
19.0 0.0526 30.21092 31.29675
26.0 0.0385 30.48022 31.58343
37.0 . . .
