#------------------------------------------------------------------------------
#$Date: 2025-07-01 14:40:50 +0300 (Tue, 01 Jul 2025) $
#$Revision: 1313 $
#$URL: svn://crystallography.net/testcod/cif/4/10/00/4100028.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4100028
loop_
_publ_author_name
'Francisco, Melanie C.'
'Malliakas, Christos D.'
'Piccoli, Paula M. B.'
'Gutmann, Matthias J.'
'Schultz, Arthur J.'
'Kanatzidis, Mercouri G.'
_publ_section_title
;
 Development and Loss of Ferromagnetism Controlled by the Interplay of Ge
 Concentration and Mn Vacancies in Structurally Modulated
 Y4Mn1−xGa12−yGey
;
_journal_issue                   26
_journal_name_full               'Journal of the American Chemical Society'
_journal_page_first              8998
_journal_page_last               9006
_journal_paper_doi               10.1021/ja1009986
_journal_volume                  132
_journal_year                    2010
_chemical_formula_sum            'Ga10.98 Ge1.02 Mn0.9 Y4'
_chemical_formula_weight         1244.88
_space_group_IT_number           229
_space_group_name_Hall           '-I 4 2 3'
_space_group_name_H-M_alt        'I m -3 m'
_symmetry_cell_setting           cubic
_symmetry_space_group_name_H-M   'I m -3 m'
_audit_creation_date             2009-10-22T15:01
_audit_creation_method           'from EXP file using GSAS2CIF'
_audit_update_record
' 2008-10-22T15:01  Initial CIF as created by GSAS2CIF'
_cell_angle_alpha                90.0
_cell_angle_beta                 90.0
_cell_angle_gamma                90.0
_cell_formula_units_Z            2
_cell_length_a                   8.5980(27)
_cell_length_b                   8.5980(27)
_cell_length_c                   8.5980(27)
_cell_measurement_reflns_used    220
_cell_measurement_temperature    260
_cell_volume                     635.6(3)
_computing_cell_refinement       'SXD 2001 (local program)'
_computing_data_collection
;
ISIS SXD time-of-flight neutron Laue diffractometer   (Gutmann,M)
;
_computing_structure_refinement  'GSAS (Larson & Von Dreele, 2004)'
_diffrn_ambient_temperature      260(1)
_diffrn_measured_fraction_theta_full 'not applicable to TOF Laue technique'
_diffrn_measured_fraction_theta_max 'not applicable to TOF Laue technique'
_diffrn_measurement_device_type  SXD
_diffrn_measurement_method       'Time-of-flight Laue'
_diffrn_radiation_monochromator  'not applicable to TOF Laue technique'
_diffrn_radiation_source         'ISIS Pulsed Neutron Source'
_diffrn_radiation_type           neutron
_diffrn_radiation_wavelength     0.37-8.8
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            1682
_diffrn_reflns_theta_full        'not applicable to TOF Laue technique'
_diffrn_reflns_theta_max         'not applicable to TOF Laue technique'
_diffrn_reflns_theta_min         'not applicable to TOF Laue technique'
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    '0.367 + 0.087 \l cm^-1^'
_exptl_absorpt_correction_T_max  0.9703
_exptl_absorpt_correction_T_min  0.9444
_exptl_absorpt_correction_type   Gaussian
_exptl_absorpt_process_details   'SXD 2001;(local program)'
_exptl_crystal_colour            silver
_exptl_crystal_density_diffrn    6.504
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_size_max          1.3
_exptl_crystal_size_mid          1.3
_exptl_crystal_size_min          1.3
_pd_block_id
2009-10-22T15:01|260K|Melanie_C._Francisco|Overall
_pd_phase_name                   'Y4Mn1-xGa12-yGey SXD T=260K'
_refine_diff_density_max         '1.58 fm \%A^-3^'
_refine_diff_density_min         '-0.56 fm \%A^-3^'
_refine_ls_extinction_method     Gaussian-Mixed
_refine_ls_goodness_of_fit_all   1.75
_refine_ls_matrix_type           full
_refine_ls_number_constraints    10
_refine_ls_number_parameters     13
_refine_ls_number_reflns         1650
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.066
_refine_ls_R_factor_gt           0.066
_refine_ls_shift/su_max          0.00
_refine_ls_shift/su_mean         0.00
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     'calc w=1/[\sFo²]²'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.133
_reflns_d_resolution_high        0.388
_reflns_d_resolution_low         6.080
_reflns_limit_h_max              22
_reflns_limit_h_min              -22
_reflns_limit_k_max              20
_reflns_limit_k_min              -18
_reflns_limit_l_max              10
_reflns_limit_l_min              -20
_reflns_number_gt                1644
_reflns_number_total             1682
_reflns_threshold_expression     I>3σ(I)
_cod_data_source_file            ja1009986_si_004.cif
_cod_data_source_block           260K_publ
_cod_original_cell_volume        635.61(35)
_cod_original_formula_sum        'Ga10.98 Ge1.02 Mn0.90 Y4'
_cod_database_code               4100028
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +x,+y,+z
2 +z,+x,+y
3 +y,+z,+x
4 +x,+y,-z
5 -z,+x,+y
6 +y,-z,+x
7 -z,+x,-y
8 -y,-z,+x
9 +y,-z,-x
10 -x,+y,-z
11 -z,-x,+y
12 +x,-y,-z
13 +y,+x,+z
14 +z,+y,+x
15 +x,+z,+y
16 +y,+x,-z
17 -z,+y,+x
18 +x,-z,+y
19 -z,+y,-x
20 -x,-z,+y
21 +x,-z,-y
22 -y,+x,-z
23 -z,-y,+x
24 +y,-x,-z
-1 -x,-y,-z
-2 -z,-x,-y
-3 -y,-z,-x
-4 -x,-y,+z
-5 +z,-x,-y
-6 -y,+z,-x
-7 +z,-x,+y
-8 +y,+z,-x
-9 -y,+z,+x
-10 +x,-y,+z
-11 +z,+x,-y
-12 -x,+y,+z
-13 -y,-x,-z
-14 -z,-y,-x
-15 -x,-z,-y
-16 -y,-x,+z
-17 +z,-y,-x
-18 -x,+z,-y
-19 +z,-y,+x
-20 +x,+z,-y
-21 -x,+z,+y
-22 +y,-x,+z
-23 +z,+y,-x
-24 -y,+x,+z
101 +x+1/2,+y+1/2,+z+1/2
102 +z+1/2,+x+1/2,+y+1/2
103 +y+1/2,+z+1/2,+x+1/2
104 +x+1/2,+y+1/2,-z+1/2
105 -z+1/2,+x+1/2,+y+1/2
106 +y+1/2,-z+1/2,+x+1/2
107 -z+1/2,+x+1/2,-y+1/2
108 -y+1/2,-z+1/2,+x+1/2
109 +y+1/2,-z+1/2,-x+1/2
110 -x+1/2,+y+1/2,-z+1/2
111 -z+1/2,-x+1/2,+y+1/2
112 +x+1/2,-y+1/2,-z+1/2
113 +y+1/2,+x+1/2,+z+1/2
114 +z+1/2,+y+1/2,+x+1/2
115 +x+1/2,+z+1/2,+y+1/2
116 +y+1/2,+x+1/2,-z+1/2
117 -z+1/2,+y+1/2,+x+1/2
118 +x+1/2,-z+1/2,+y+1/2
119 -z+1/2,+y+1/2,-x+1/2
120 -x+1/2,-z+1/2,+y+1/2
121 +x+1/2,-z+1/2,-y+1/2
122 -y+1/2,+x+1/2,-z+1/2
123 -z+1/2,-y+1/2,+x+1/2
124 +y+1/2,-x+1/2,-z+1/2
-101 -x+1/2,-y+1/2,-z+1/2
-102 -z+1/2,-x+1/2,-y+1/2
-103 -y+1/2,-z+1/2,-x+1/2
-104 -x+1/2,-y+1/2,+z+1/2
-105 +z+1/2,-x+1/2,-y+1/2
-106 -y+1/2,+z+1/2,-x+1/2
-107 +z+1/2,-x+1/2,+y+1/2
-108 +y+1/2,+z+1/2,-x+1/2
-109 -y+1/2,+z+1/2,+x+1/2
-110 +x+1/2,-y+1/2,+z+1/2
-111 +z+1/2,+x+1/2,-y+1/2
-112 -x+1/2,+y+1/2,+z+1/2
-113 -y+1/2,-x+1/2,-z+1/2
-114 -z+1/2,-y+1/2,-x+1/2
-115 -x+1/2,-z+1/2,-y+1/2
-116 -y+1/2,-x+1/2,+z+1/2
-117 +z+1/2,-y+1/2,-x+1/2
-118 -x+1/2,+z+1/2,-y+1/2
-119 +z+1/2,-y+1/2,+x+1/2
-120 +x+1/2,+z+1/2,-y+1/2
-121 -x+1/2,+z+1/2,+y+1/2
-122 +y+1/2,-x+1/2,+z+1/2
-123 +z+1/2,+y+1/2,-x+1/2
-124 -y+1/2,+x+1/2,+z+1/2
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_thermal_displace_type
_atom_site_U_iso_or_equiv
_atom_site_symmetry_multiplicity
Y Y 0.25 0.25 0.25 1.0 Uani 0.00609 8
Mn Mn 0.0 0.0 0.0 0.904(30) Uani 0.00943 2
Ga Ga1 0.25 0.0 0.5 1.0 Uani 0.00609 12
Ga Ga2 0.28950(15) 0.0 0.0 0.83(6) Uani 0.00807 12
Ge Ge2 0.28950(15) 0.0 0.0 0.17(6) Uani 0.00807 12
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
? ? ? ? ?
loop_
_diffrn_standard_refln_index_h
_diffrn_standard_refln_index_k
_diffrn_standard_refln_index_l
? ? ?
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Ga1 Y Ga1 120.000(15) 1_555 . 2_555 N
Ga1 Y Ga1 120.000(7) 1_555 . 3_555 N
Ga1 Y Ga1 60.000(15) 1_555 . 13_555 N
Ga1 Y Ga1 60.000(7) 1_555 . 14_555 N
Ga1 Y Ga1 180.0 1_555 . 15_555 N
Ga1 Y Ga2 90.000(25) 1_555 . 1_555 N
Ga1 Y Ga2 125.129(23) 1_555 . 2_555 N
Ga1 Y Ga2 54.871(20) 1_555 . 3_555 N
Ga1 Y Ga2 125.129(20) 1_555 . 109_555 N
Ga1 Y Ga2 90.000(25) 1_555 . 110_555 N
Ga1 Y Ga2 54.871(23) 1_555 . 111_555 N
Ga1 Y Ge2 90.000(25) 1_555 . 1_555 N
Ga1 Y Ge2 125.129(23) 1_555 . 2_555 N
Ga1 Y Ge2 54.871(20) 1_555 . 3_555 N
Ga1 Y Ge2 125.129(20) 1_555 . 109_555 N
Ga1 Y Ge2 90.000(25) 1_555 . 110_555 N
Ga1 Y Ge2 54.871(23) 1_555 . 111_555 N
Ga1 Y Ga1 120.000(7) 2_555 . 3_555 N
Ga1 Y Ga1 180.0 2_555 . 13_555 N
Ga1 Y Ga1 60.000(7) 2_555 . 14_555 N
Ga1 Y Ga1 60.000(15) 2_555 . 15_555 N
Ga1 Y Ga2 54.871(23) 2_555 . 1_555 N
Ga1 Y Ga2 90.000(25) 2_555 . 2_555 N
Ga1 Y Ga2 125.129(20) 2_555 . 3_555 N
Ga1 Y Ga2 54.871(20) 2_555 . 109_555 N
Ga1 Y Ga2 125.129(23) 2_555 . 110_555 N
Ga1 Y Ga2 90.000(25) 2_555 . 111_555 N
Ga1 Y Ge2 54.871(23) 2_555 . 1_555 N
Ga1 Y Ge2 90.000(25) 2_555 . 2_555 N
Ga1 Y Ge2 125.129(20) 2_555 . 3_555 N
Ga1 Y Ge2 54.871(20) 2_555 . 109_555 N
Ga1 Y Ge2 125.129(23) 2_555 . 110_555 N
Ga1 Y Ge2 90.000(25) 2_555 . 111_555 N
Ga1 Y Ga1 60.000(7) 3_555 . 13_555 N
Ga1 Y Ga1 180.0 3_555 . 14_555 N
Ga1 Y Ga1 60.000(7) 3_555 . 15_555 N
Ga1 Y Ga2 125.129(21) 3_555 . 1_555 N
Ga1 Y Ga2 54.871(21) 3_555 . 2_555 N
Ga1 Y Ga2 90.0 3_555 . 3_555 N
Ga1 Y Ga2 90.0 3_555 . 109_555 N
Ga1 Y Ga2 54.871(21) 3_555 . 110_555 N
Ga1 Y Ga2 125.129(21) 3_555 . 111_555 N
Ga1 Y Ge2 125.129(21) 3_555 . 1_555 N
Ga1 Y Ge2 54.871(21) 3_555 . 2_555 N
Ga1 Y Ge2 90.0 3_555 . 3_555 N
Ga1 Y Ge2 90.0 3_555 . 109_555 N
Ga1 Y Ge2 54.871(21) 3_555 . 110_555 N
Ga1 Y Ge2 125.129(21) 3_555 . 111_555 N
Ga1 Y Ga1 120.000(7) 13_555 . 14_555 N
Ga1 Y Ga1 120.000(15) 13_555 . 15_555 N
Ga1 Y Ga2 125.129(23) 13_555 . 1_555 N
Ga1 Y Ga2 90.000(25) 13_555 . 2_555 N
Ga1 Y Ga2 54.871(20) 13_555 . 3_555 N
Ga1 Y Ga2 125.129(20) 13_555 . 109_555 N
Ga1 Y Ga2 54.871(23) 13_555 . 110_555 N
Ga1 Y Ga2 90.000(25) 13_555 . 111_555 N
Ga1 Y Ge2 125.129(23) 13_555 . 1_555 N
Ga1 Y Ge2 90.000(25) 13_555 . 2_555 N
Ga1 Y Ge2 54.871(20) 13_555 . 3_555 N
Ga1 Y Ge2 125.129(20) 13_555 . 109_555 N
Ga1 Y Ge2 54.871(23) 13_555 . 110_555 N
Ga1 Y Ge2 90.000(25) 13_555 . 111_555 N
Ga1 Y Ga1 120.000(7) 14_555 . 15_555 N
Ga1 Y Ga2 54.871(21) 14_555 . 1_555 N
Ga1 Y Ga2 125.129(21) 14_555 . 2_555 N
Ga1 Y Ga2 90.0 14_555 . 3_555 N
Ga1 Y Ga2 90.0 14_555 . 109_555 N
Ga1 Y Ga2 125.129(21) 14_555 . 110_555 N
Ga1 Y Ga2 54.871(21) 14_555 . 111_555 N
Ga1 Y Ge2 54.871(21) 14_555 . 1_555 N
Ga1 Y Ge2 125.129(21) 14_555 . 2_555 N
Ga1 Y Ge2 90.0 14_555 . 3_555 N
Ga1 Y Ge2 90.0 14_555 . 109_555 N
Ga1 Y Ge2 125.129(21) 14_555 . 110_555 N
Ga1 Y Ge2 54.871(21) 14_555 . 111_555 N
Ga1 Y Ga2 90.000(25) 15_555 . 1_555 N
Ga1 Y Ga2 54.871(23) 15_555 . 2_555 N
Ga1 Y Ga2 125.129(20) 15_555 . 3_555 N
Ga1 Y Ga2 54.871(20) 15_555 . 109_555 N
Ga1 Y Ga2 90.000(25) 15_555 . 110_555 N
Ga1 Y Ga2 125.129(23) 15_555 . 111_555 N
Ga1 Y Ge2 90.000(25) 15_555 . 1_555 N
Ga1 Y Ge2 54.871(23) 15_555 . 2_555 N
Ga1 Y Ge2 125.129(20) 15_555 . 3_555 N
Ga1 Y Ge2 54.871(20) 15_555 . 109_555 N
Ga1 Y Ge2 90.000(25) 15_555 . 110_555 N
Ga1 Y Ge2 125.129(23) 15_555 . 111_555 N
Ga2 Y Ga2 70.26(4) 1_555 . 2_555 N
Ga2 Y Ga2 70.26(4) 1_555 . 3_555 N
Ga2 Y Ga2 109.74(4) 1_555 . 109_555 N
Ga2 Y Ga2 179.9802 1_555 . 110_555 N
Ga2 Y Ga2 109.74(4) 1_555 . 111_555 N
Ga2 Y Ge2 0.0 1_555 . 1_555 N
Ga2 Y Ge2 70.26(4) 1_555 . 2_555 N
Ga2 Y Ge2 70.26(4) 1_555 . 3_555 N
Ga2 Y Ge2 109.74(4) 1_555 . 109_555 N
Ga2 Y Ge2 179.9802 1_555 . 110_555 N
Ga2 Y Ge2 109.74(4) 1_555 . 111_555 N
Ga2 Y Ga2 70.26(4) 2_555 . 3_555 N
Ga2 Y Ga2 109.74(4) 2_555 . 109_555 N
Ga2 Y Ga2 109.74(4) 2_555 . 110_555 N
Ga2 Y Ga2 179.9802 2_555 . 111_555 N
Ga2 Y Ge2 70.26(4) 2_555 . 1_555 N
Ga2 Y Ge2 0.0 2_555 . 2_555 N
Ga2 Y Ge2 70.26(4) 2_555 . 3_555 N
Ga2 Y Ge2 109.74(4) 2_555 . 109_555 N
Ga2 Y Ge2 109.74(4) 2_555 . 110_555 N
Ga2 Y Ge2 179.9802 2_555 . 111_555 N
Ga2 Y Ga2 179.9802 3_555 . 109_555 N
Ga2 Y Ga2 109.74(4) 3_555 . 110_555 N
Ga2 Y Ga2 109.74(4) 3_555 . 111_555 N
Ga2 Y Ge2 70.26(4) 3_555 . 1_555 N
Ga2 Y Ge2 70.26(4) 3_555 . 2_555 N
Ga2 Y Ge2 0.0 3_555 . 3_555 N
Ga2 Y Ge2 179.9802 3_555 . 109_555 N
Ga2 Y Ge2 109.74(4) 3_555 . 110_555 N
Ga2 Y Ge2 109.74(4) 3_555 . 111_555 N
Ga2 Y Ga2 70.26(4) 109_555 . 110_555 N
Ga2 Y Ga2 70.26(4) 109_555 . 111_555 N
Ga2 Y Ge2 109.74(4) 109_555 . 1_555 N
Ga2 Y Ge2 109.74(4) 109_555 . 2_555 N
Ga2 Y Ge2 179.9802 109_555 . 3_555 N
Ga2 Y Ge2 0.0 109_555 . 109_555 N
Ga2 Y Ge2 70.26(4) 109_555 . 110_555 N
Ga2 Y Ge2 70.26(4) 109_555 . 111_555 N
Ga2 Y Ga2 70.26(4) 110_555 . 111_555 N
Ga2 Y Ge2 179.9802 110_555 . 1_555 N
Ga2 Y Ge2 109.74(4) 110_555 . 2_555 N
Ga2 Y Ge2 109.74(4) 110_555 . 3_555 N
Ga2 Y Ge2 70.26(4) 110_555 . 109_555 N
Ga2 Y Ge2 0.0 110_555 . 110_555 N
Ga2 Y Ge2 70.26(4) 110_555 . 111_555 N
Ga2 Y Ge2 109.74(4) 111_555 . 1_555 N
Ga2 Y Ge2 179.9802 111_555 . 2_555 N
Ga2 Y Ge2 109.74(4) 111_555 . 3_555 N
Ga2 Y Ge2 70.26(4) 111_555 . 109_555 N
Ga2 Y Ge2 70.26(4) 111_555 . 110_555 N
Ga2 Y Ge2 0.0 111_555 . 111_555 N
Ge2 Y Ge2 70.26(4) 1_555 . 2_555 N
Ge2 Y Ge2 70.26(4) 1_555 . 3_555 N
Ge2 Y Ge2 109.74(4) 1_555 . 109_555 N
Ge2 Y Ge2 179.9802 1_555 . 110_555 N
Ge2 Y Ge2 109.74(4) 1_555 . 111_555 N
Ge2 Y Ge2 70.26(4) 2_555 . 3_555 N
Ge2 Y Ge2 109.74(4) 2_555 . 109_555 N
Ge2 Y Ge2 109.74(4) 2_555 . 110_555 N
Ge2 Y Ge2 179.9802 2_555 . 111_555 N
Ge2 Y Ge2 179.9802 3_555 . 109_555 N
Ge2 Y Ge2 109.74(4) 3_555 . 110_555 N
Ge2 Y Ge2 109.74(4) 3_555 . 111_555 N
Ge2 Y Ge2 70.26(4) 109_555 . 110_555 N
Ge2 Y Ge2 70.26(4) 109_555 . 111_555 N
Ge2 Y Ge2 70.26(4) 110_555 . 111_555 N
Ga2 Mn Ga2 90.0 1_555 . 2_555 N
Ga2 Mn Ga2 90.0 1_555 . 3_555 N
Ga2 Mn Ga2 90.0 1_555 . 9_555 N
Ga2 Mn Ga2 180.0 1_555 . 10_555 N
Ga2 Mn Ga2 90.0 1_555 . 11_555 N
Ga2 Mn Ge2 0.0 1_555 . 1_555 N
Ga2 Mn Ge2 90.0 1_555 . 2_555 N
Ga2 Mn Ge2 90.0 1_555 . 3_555 N
Ga2 Mn Ge2 90.0 1_555 . 9_555 N
Ga2 Mn Ge2 180.0 1_555 . 10_555 N
Ga2 Mn Ge2 90.0 1_555 . 11_555 N
Ga2 Mn Ga2 90.0 2_555 . 3_555 N
Ga2 Mn Ga2 90.0 2_555 . 9_555 N
Ga2 Mn Ga2 90.0 2_555 . 10_555 N
Ga2 Mn Ga2 180.0 2_555 . 11_555 N
Ga2 Mn Ge2 90.0 2_555 . 1_555 N
Ga2 Mn Ge2 0.0 2_555 . 2_555 N
Ga2 Mn Ge2 90.0 2_555 . 3_555 N
Ga2 Mn Ge2 90.0 2_555 . 9_555 N
Ga2 Mn Ge2 90.0 2_555 . 10_555 N
Ga2 Mn Ge2 180.0 2_555 . 11_555 N
Ga2 Mn Ga2 180.0 3_555 . 9_555 N
Ga2 Mn Ga2 90.0 3_555 . 10_555 N
Ga2 Mn Ga2 90.0 3_555 . 11_555 N
Ga2 Mn Ge2 90.0 3_555 . 1_555 N
Ga2 Mn Ge2 90.0 3_555 . 2_555 N
Ga2 Mn Ge2 0.0 3_555 . 3_555 N
Ga2 Mn Ge2 180.0 3_555 . 9_555 N
Ga2 Mn Ge2 90.0 3_555 . 10_555 N
Ga2 Mn Ge2 90.0 3_555 . 11_555 N
Ga2 Mn Ga2 90.0 9_555 . 10_555 N
Ga2 Mn Ga2 90.0 9_555 . 11_555 N
Ga2 Mn Ge2 90.0 9_555 . 1_555 N
Ga2 Mn Ge2 90.0 9_555 . 2_555 N
Ga2 Mn Ge2 180.0 9_555 . 3_555 N
Ga2 Mn Ge2 0.0 9_555 . 9_555 N
Ga2 Mn Ge2 90.0 9_555 . 10_555 N
Ga2 Mn Ge2 90.0 9_555 . 11_555 N
Ga2 Mn Ga2 90.0 10_555 . 11_555 N
Ga2 Mn Ge2 180.0 10_555 . 1_555 N
Ga2 Mn Ge2 90.0 10_555 . 2_555 N
Ga2 Mn Ge2 90.0 10_555 . 3_555 N
Ga2 Mn Ge2 90.0 10_555 . 9_555 N
Ga2 Mn Ge2 0.0 10_555 . 10_555 N
Ga2 Mn Ge2 90.0 10_555 . 11_555 N
Ga2 Mn Ge2 90.0 11_555 . 1_555 N
Ga2 Mn Ge2 180.0 11_555 . 2_555 N
Ga2 Mn Ge2 90.0 11_555 . 3_555 N
Ga2 Mn Ge2 90.0 11_555 . 9_555 N
Ga2 Mn Ge2 90.0 11_555 . 10_555 N
Ga2 Mn Ge2 0.0 11_555 . 11_555 N
Ge2 Mn Ge2 90.0 1_555 . 2_555 N
Ge2 Mn Ge2 90.0 1_555 . 3_555 N
Ge2 Mn Ge2 90.0 1_555 . 9_555 N
Ge2 Mn Ge2 180.0 1_555 . 10_555 N
Ge2 Mn Ge2 90.0 1_555 . 11_555 N
Ge2 Mn Ge2 90.0 2_555 . 3_555 N
Ge2 Mn Ge2 90.0 2_555 . 9_555 N
Ge2 Mn Ge2 90.0 2_555 . 10_555 N
Ge2 Mn Ge2 180.0 2_555 . 11_555 N
Ge2 Mn Ge2 180.0 3_555 . 9_555 N
Ge2 Mn Ge2 90.0 3_555 . 10_555 N
Ge2 Mn Ge2 90.0 3_555 . 11_555 N
Ge2 Mn Ge2 90.0 9_555 . 10_555 N
Ge2 Mn Ge2 90.0 9_555 . 11_555 N
Ge2 Mn Ge2 90.0 10_555 . 11_555 N
Y Ga1 Y 90.000(25) 1_555 . 4_556 N
Y Ga1 Y 90.000(25) 1_555 . 6_555 N
Y Ga1 Y 180.0 1_555 . 9_556 N
Y Ga1 Ga2 62.907(19) 1_555 . 3_555 N
Y Ga1 Ga2 117.093(19) 1_555 . 9_556 N
Y Ga1 Ga2 117.093(14) 1_555 . 102_545 N
Y Ga1 Ga2 62.907(14) 1_555 . 111_555 N
Y Ga1 Y 180.0 4_556 . 6_555 N
Y Ga1 Y 90.000(25) 4_556 . 9_556 N
Y Ga1 Ga2 117.093(19) 4_556 . 3_555 N
Y Ga1 Ga2 62.907(19) 4_556 . 9_556 N
Y Ga1 Ga2 117.093(14) 4_556 . 102_545 N
Y Ga1 Ga2 62.907(14) 4_556 . 111_555 N
Y Ga1 Y 90.000(25) 6_555 . 9_556 N
Y Ga1 Ga2 62.907(19) 6_555 . 3_555 N
Y Ga1 Ga2 117.093(19) 6_555 . 9_556 N
Y Ga1 Ga2 62.907(14) 6_555 . 102_545 N
Y Ga1 Ga2 117.093(14) 6_555 . 111_555 N
Y Ga1 Ga2 117.093(19) 9_556 . 3_555 N
Y Ga1 Ga2 62.907(19) 9_556 . 9_556 N
Y Ga1 Ga2 62.907(14) 9_556 . 102_545 N
Y Ga1 Ga2 117.093(14) 9_556 . 111_555 N
Ga2 Ga1 Ga2 80.20(5) 3_555 . 9_556 N
Ga2 Ga1 Ga2 125.813(26) 3_555 . 102_545 N
Ga2 Ga1 Ga2 125.813(26) 3_555 . 111_555 N
Ga2 Ga1 Ga2 125.813(26) 9_556 . 102_545 N
Ga2 Ga1 Ga2 125.813(26) 9_556 . 111_555 N
Ga2 Ga1 Ga2 80.20(4) 102_545 . 111_555 N
Y Ga2 Y 89.294(26) 1_555 . 4_555 N
Y Ga2 Y 89.294(25) 1_555 . 6_555 N
Y Ga2 Y 167.25(5) 1_555 . 9_555 N
Y Ga2 Mn 83.626(25) 1_555 . 1_555 N
Y Ga2 Ga1 62.222(10) 1_555 . 2_555 N
Y Ga2 Ga1 127.522(29) 1_555 . 11_655 N
Y Ga2 Ga1 62.222(18) 1_555 . 14_555 N
Y Ga2 Ga1 127.522(31) 1_555 . 19_655 N
Y Ga2 Y 167.25(5) 4_555 . 6_555 N
Y Ga2 Y 89.294(25) 4_555 . 9_555 N
Y Ga2 Mn 83.626(25) 4_555 . 1_555 N
Y Ga2 Ga1 62.222(10) 4_555 . 2_555 N
Y Ga2 Ga1 127.522(29) 4_555 . 11_655 N
Y Ga2 Ga1 127.522(31) 4_555 . 14_555 N
Y Ga2 Ga1 62.222(18) 4_555 . 19_655 N
Y Ga2 Y 89.294(26) 6_555 . 9_555 N
Y Ga2 Mn 83.626(25) 6_555 . 1_555 N
Y Ga2 Ga1 127.522(29) 6_555 . 2_555 N
Y Ga2 Ga1 62.222(10) 6_555 . 11_655 N
Y Ga2 Ga1 62.222(18) 6_555 . 14_555 N
Y Ga2 Ga1 127.522(31) 6_555 . 19_655 N
Y Ga2 Mn 83.626(25) 9_555 . 1_555 N
Y Ga2 Ga1 127.522(29) 9_555 . 2_555 N
Y Ga2 Ga1 62.222(10) 9_555 . 11_655 N
Y Ga2 Ga1 127.522(31) 9_555 . 14_555 N
Y Ga2 Ga1 62.222(18) 9_555 . 19_655 N
Mn Ga2 Ga1 130.098(21) 1_555 . 2_555 N
Mn Ga2 Ga1 130.098(21) 1_555 . 11_655 N
Mn Ga2 Ga1 130.098(24) 1_555 . 14_555 N
Mn Ga2 Ga1 130.098(24) 1_555 . 19_655 N
Ga1 Ga2 Ga1 99.80(4) 2_555 . 11_655 N
Ga1 Ga2 Ga1 65.490(23) 2_555 . 14_555 N
Ga1 Ga2 Ga1 65.490(23) 2_555 . 19_655 N
Ga1 Ga2 Ga1 65.490(23) 11_655 . 14_555 N
Ga1 Ga2 Ga1 65.490(23) 11_655 . 19_655 N
Ga1 Ga2 Ga1 99.80(5) 14_555 . 19_655 N
Y Ge2 Y 89.294(26) 1_555 . 4_555 N
Y Ge2 Y 89.294(25) 1_555 . 6_555 N
Y Ge2 Y 167.25(5) 1_555 . 9_555 N
Y Ge2 Mn 83.626(25) 1_555 . 1_555 N
Y Ge2 Y 167.25(5) 4_555 . 6_555 N
Y Ge2 Y 89.294(25) 4_555 . 9_555 N
Y Ge2 Mn 83.626(25) 4_555 . 1_555 N
Y Ge2 Y 89.294(26) 6_555 . 9_555 N
Y Ge2 Mn 83.626(25) 6_555 . 1_555 N
Y Ge2 Mn 83.626(25) 9_555 . 1_555 N
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Y Ga1 3.0398(7) . 1_555 N
Y Ga1 3.0398(7) . 2_555 N
Y Ga1 3.0398(10) . 3_555 N
Y Ga1 3.0398(7) . 13_555 N
Y Ga1 3.0398(10) . 14_555 N
Y Ga1 3.0398(7) . 15_555 N
Y Ga2 3.0588(7) . 1_555 N
Y Ga2 3.0588(7) . 2_555 N
Y Ga2 3.0588(10) . 3_555 N
Y Ga2 3.0588(10) . 109_555 N
Y Ga2 3.0588(7) . 110_555 N
Y Ga2 3.0588(7) . 111_555 N
Y Ge2 3.0588(7) . 1_555 N
Y Ge2 3.0588(7) . 2_555 N
Y Ge2 3.0588(10) . 3_555 N
Y Ge2 3.0588(10) . 109_555 N
Y Ge2 3.0588(7) . 110_555 N
Y Ge2 3.0588(7) . 111_555 N
Mn Ga2 2.4891(15) . 1_555 N
Mn Ga2 2.4891(15) . 2_555 N
Mn Ga2 2.4891(15) . 3_555 N
Mn Ga2 2.4891(15) . 9_555 N
Mn Ga2 2.4891(15) . 10_555 N
Mn Ga2 2.4891(15) . 11_555 N
Mn Ge2 2.4891(15) . 1_555 N
Mn Ge2 2.4891(15) . 2_555 N
Mn Ge2 2.4891(15) . 3_555 N
Mn Ge2 2.4891(15) . 9_555 N
Mn Ge2 2.4891(15) . 10_555 N
Mn Ge2 2.4891(15) . 11_555 N
Ga1 Y 3.0398(7) . 1_555 N
Ga1 Y 3.0398(7) . 4_556 N
Ga1 Y 3.0398(7) . 6_555 N
Ga1 Y 3.0398(7) . 9_556 N
Ga1 Ga1 3.0398(10) . 13_555 N
Ga1 Ga1 3.0398(7) . 14_555 N
Ga1 Ga1 3.0398(7) . 19_656 N
Ga1 Ga1 3.0398(10) . 24_556 N
Ga1 Ga2 2.8100(11) . 3_555 N
Ga1 Ga2 2.8100(11) . 9_556 N
Ga1 Ga2 2.8100(12) . 102_545 N
Ga1 Ga2 2.8100(12) . 111_555 N
Ga1 Ge2 2.8100(11) . 3_555 N
Ga1 Ge2 2.8100(11) . 9_556 N
Ga1 Ge2 2.8100(12) . 102_545 N
Ga1 Ge2 2.8100(12) . 111_555 N
Ga2 Y 3.0588(7) . 1_555 N
Ga2 Y 3.0588(7) . 4_555 N
Ga2 Y 3.0588(7) . 6_555 N
Ga2 Y 3.0588(7) . 9_555 N
Ga2 Mn 2.4891(15) . 1_555 N
Ga2 Ga1 2.8100(12) . 2_555 N
Ga2 Ga1 2.8100(12) . 11_655 N
Ga2 Ga1 2.8100(11) . 14_555 N
Ga2 Ga1 2.8100(11) . 19_655 N
Ge2 Y 3.0588(7) . 1_555 N
Ge2 Y 3.0588(7) . 4_555 N
Ge2 Y 3.0588(7) . 6_555 N
Ge2 Y 3.0588(7) . 9_555 N
Ge2 Mn 2.4891(15) . 1_555 N
Ge2 Ga1 2.8100(12) . 2_555 N
Ge2 Ga1 2.8100(12) . 11_655 N
Ge2 Ga1 2.8100(11) . 14_555 N
Ge2 Ga1 2.8100(11) . 19_655 N
