#------------------------------------------------------------------------------
#$Date: 2025-07-01 14:24:49 +0300 (Tue, 01 Jul 2025) $
#$Revision: 1247 $
#$URL: svn://crystallography.net/testcod/cif/4/00/00/4000036.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4000036
loop_
_publ_author_name
'Ngala, J. Katana'
'Alia, Shaun'
'Dobley, Arthur'
'Crisostomo, Vincent Mark B.'
'Suib, Steven L.'
_publ_section_title
;
 Characterization and Electrocatalytic Behavior of Layered Li2MnO3and Its
 Acid-Treated Form
;
_journal_issue                   2
_journal_name_full               'Chemistry of Materials'
_journal_page_first              229
_journal_page_last               234
_journal_paper_doi               10.1021/cm0616937
_journal_volume                  19
_journal_year                    2007
_chemical_formula_sum            'Li0.11 Mn0.34 O'
_chemical_formula_weight         35.29
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_audit_creation_date             2006-10-28T18:56
_audit_creation_method           'from EXP file using GSAS2CIF'
_audit_update_record
' 2006-10-28T18:56  Initial CIF as created by GSAS2CIF'
_cell_angle_alpha                90.0
_cell_angle_beta                 109.196(16)
_cell_angle_gamma                90.0
_cell_formula_units_Z            12
_cell_length_a                   5.0512(12)
_cell_length_b                   8.7065(18)
_cell_length_c                   4.9045(9)
_cell_volume                     203.70(8)
_computing_structure_refinement  GSAS
_diffrn_radiation_polarisn_ratio 0.5
_diffrn_radiation_probe          x-ray
_exptl_absorpt_correction_T_max  0.88647
_exptl_absorpt_correction_T_min  0.51506
_exptl_absorpt_process_details
;   GSAS Absorption/surface roughness correction: function number 3
 Surface roughness abs. correction (Suortti)
Terms =     0.32975        0.34355    
Correction is not refined.
;
_pd_block_id
2006-10-28T18:56|LI2MN_22M_3|Katana_Ngala|Scintag_XDS2000
_pd_calc_method                  'Rietveld Refinement'
_pd_instr_location               ' ?'
_pd_meas_2theta_range_inc        0.02
_pd_meas_2theta_range_max        70.0
_pd_meas_2theta_range_min        10.0
_pd_meas_number_of_points        3001
_pd_phase_name
'from C:/Documents and Settings/John Ngala/My Documents/Refinement/'
_pd_proc_2theta_range_inc        0.02
_pd_proc_2theta_range_max        70.0
_pd_proc_2theta_range_min        10.0
_pd_proc_info_datetime           2006-10-28T18:56:41
_pd_proc_info_excluded_regions   ' ?'
_pd_proc_ls_background_function
;   GSAS Background function number 1 with  6 terms.
 Shifted Chebyshev function of 1st kind
      1:    127.152     2:   -86.6443     3:    44.2547     4:   -11.3998    
      5:   -9.89408     6:    7.47054    
;
_pd_proc_ls_peak_cutoff          0.00500
_pd_proc_ls_pref_orient_corr
;   March-Dollase
 AXIS  1 Ratio=   0.98572  h= 0.000  k= 0.000  l= 1.000
 Prefered orientation correction range: Min=   0.97865, Max=   1.04410
;
_pd_proc_ls_profile_function
;
 CW Profile function number 2 with  18 terms
 Profile coefficients for Simpson's rule integration of pseudovoigt function
 C.J. Howard (1982). J. Appl. Cryst.,15,615-620.
 P. Thompson, D.E. Cox & J.B. Hastings (1987). J. Appl. Cryst.,20,79-83.
 #1(GU)   =    0.000 #2(GV)   =   -0.957 #3(GW)   =  -81.492
 #4(LX)   =    0.000 #5(LY)   =   84.944 #6(trns) =    0.000
 #7(asym) =  -0.9715 #8(shft) = -14.8451 #9(GP)   =    0.000
 #10(stec)=    66.46 #11(ptec)=     0.00 #12(sfec)=     0.00
 #13(L11) =    0.209 #14(L22) =    0.131 #15(L33) =    0.000
 #16(L12) =    0.375 #17(L13) =    0.081 #18(L23) =    0.000
 Peak tails are ignored  where the intensity is below 0.0050 times the peak
   Aniso. broadening axis   0.0   0.0   1.0
;
_pd_proc_ls_prof_R_factor        0.1095
_pd_proc_ls_prof_wR_expected     0.0688
_pd_proc_ls_prof_wR_factor       0.1361
_pd_proc_number_of_points        3001
_pd_spec_mounting                ' ?'
_refine_ls_goodness_of_fit_all   1.98
_refine_ls_matrix_type           full
_refine_ls_number_parameters     12
_refine_ls_number_restraints     0
_refine_ls_R_Fsqd_factor         0.12214
_refine_ls_shift/su_max          0.06
_refine_ls_shift/su_mean         0.02
_reflns_d_resolution_high        1.355
_reflns_d_resolution_low         4.632
_reflns_limit_h_max              4
_reflns_limit_h_min              0
_reflns_limit_k_max              6
_reflns_limit_k_min              0
_reflns_limit_l_max              3
_reflns_limit_l_min              -3
_reflns_number_total             102
_cod_data_source_file            cm0616937si20061028_081518.cif
_cod_data_source_block           LI2MN_22M_3_publ
_cod_original_cell_volume        203.70(6)
_cod_original_sg_symbol_H-M      'C 2/m'
_cod_database_code               4000036
_gsas_exptl_extinct_corr_t_min   1.00000
_gsas_exptl_extinct_corr_t_max   1.00000
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +x,+y,+z
2 -x,+y,-z
-1 -x,-y,-z
-2 +x,-y,+z
101 +x+1/2,+y+1/2,+z
102 -x+1/2,+y+1/2,-z
-101 -x+1/2,-y+1/2,-z
-102 +x+1/2,-y+1/2,+z
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_thermal_displace_type
_atom_site_U_iso_or_equiv
_atom_site_symmetry_multiplicity
Mn Mn1 0.0 0.17544 0.0 0.62825 Uiso 0.025 4
Li Li1 0.0 0.5 0.0 0.638 Uiso 0.025 2
O O1 0.11446 0.0 -0.19859 1.0 Uiso 0.025 4
O O2 0.15538 0.33593 -0.23031 1.0 Uiso 0.025 8
Mn Mn2 0.0 0.5 0.0 0.362 Uiso 0.025 2
Mn Mn3 0.0 0.75343 0.5 0.20361 Uiso 0.025 4
loop_
_atom_type_symbol
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_Cromer_Mann_a1
_atom_type_scat_Cromer_Mann_a2
_atom_type_scat_Cromer_Mann_a3
_atom_type_scat_Cromer_Mann_a4
_atom_type_scat_Cromer_Mann_b1
_atom_type_scat_Cromer_Mann_b2
_atom_type_scat_Cromer_Mann_b3
_atom_type_scat_Cromer_Mann_b4
_atom_type_scat_Cromer_Mann_c
_atom_type_scat_source
Mn 4.051 0.000 0.000 11.2819 5.34090 7.35730 0.34320 3.01930 17.8674 2.24410
83.7543 1.08960 International_Tables_Vol_C
Li 1.276 0.000 0.000 1.12820 3.95460 0.75080 1.05240 0.61750 85.3905 0.46530
168.261 0.03770 International_Tables_Vol_C
O 12.0 0.000 0.000 3.04850 13.2771 2.28680 5.70110 1.54630 0.32390 0.86700
32.9089 0.25080 International_Tables_Vol_C
loop_
_diffrn_radiation_wavelength
_diffrn_radiation_wavelength_wt
_diffrn_radiation_type
_diffrn_radiation_wavelength_id
1.540600 1.000 CuK\a~1~ 1
1.544400 0.500 CuK\a~2~ 2
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_2
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Li1 Mn1 O1 139.911(7) 1_555 . 1_555 N
Li1 Mn1 O1 139.911(7) 1_555 . 2_555 N
Li1 Mn1 O2 48.389(7) 1_555 . 1_555 N
Li1 Mn1 O2 48.389(7) 1_555 . 2_555 N
Li1 Mn1 O2 93.2657(11) 1_555 . -101_555 N
Li1 Mn1 O2 93.2657(11) 1_555 . -102_455 N
Li1 Mn1 Mn3 75.827(4) 1_555 . -1_565 N
Li1 Mn1 Mn3 75.827(4) 1_555 . -1_566 N
O1 Mn1 O1 80.178(15) 1_555 . 2_555 N
O1 Mn1 O2 91.560(15) 1_555 . 1_555 N
O1 Mn1 O2 171.4457(5) 1_555 . 2_555 N
O1 Mn1 O2 83.379(11) 1_555 . -101_555 N
O1 Mn1 O2 91.613(11) 1_555 . -102_455 N
O1 Mn1 Mn3 67.793(11) 1_555 . -1_565 N
O1 Mn1 Mn3 138.816(5) 1_555 . -1_566 N
O1 Mn1 O2 171.4457(5) 2_555 . 1_555 N
O1 Mn1 O2 91.560(15) 2_555 . 2_555 N
O1 Mn1 O2 91.613(11) 2_555 . -101_555 N
O1 Mn1 O2 83.379(11) 2_555 . -102_455 N
O1 Mn1 Mn3 138.816(5) 2_555 . -1_565 N
O1 Mn1 Mn3 67.793(11) 2_555 . -1_566 N
O2 Mn1 O2 96.777(15) 1_555 . 2_555 N
O2 Mn1 O2 85.187(13) 1_555 . -101_555 N
O2 Mn1 O2 99.181(13) 1_555 . -102_455 N
O2 Mn1 Mn3 36.678(6) 1_555 . -1_565 N
O2 Mn1 Mn3 118.477(11) 1_555 . -1_566 N
O2 Mn1 O2 99.181(13) 2_555 . -101_555 N
O2 Mn1 O2 85.187(13) 2_555 . -102_455 N
O2 Mn1 Mn3 118.477(11) 2_555 . -1_565 N
O2 Mn1 Mn3 36.678(6) 2_555 . -1_566 N
O2 Mn1 O2 173.4685(21) -101_555 . -102_455 N
O2 Mn1 Mn3 108.946(16) -101_555 . -1_565 N
O2 Mn1 Mn3 72.736(16) -101_555 . -1_566 N
O2 Mn1 Mn3 72.736(16) -102_455 . -1_565 N
O2 Mn1 Mn3 108.946(16) -102_455 . -1_566 N
Mn3 Mn1 Mn3 151.654(7) -1_565 . -1_566 N
Mn1 Li1 Mn1 180.0 1_555 . -1_565 N
Mn1 Li1 O1 90.0 1_555 . 101_455 N
Mn1 Li1 O1 90.0 1_555 . 102_555 N
Mn1 Li1 O2 47.760(7) 1_555 . 1_555 N
Mn1 Li1 O2 47.760(7) 1_555 . 2_555 N
Mn1 Li1 O2 132.240(7) 1_555 . -1_565 N
Mn1 Li1 O2 132.240(7) 1_555 . -2_565 N
Mn1 Li1 O1 90.0 -1_565 . 101_455 N
Mn1 Li1 O1 90.0 -1_565 . 102_555 N
Mn1 Li1 O2 132.240(7) -1_565 . 1_555 N
Mn1 Li1 O2 132.240(7) -1_565 . 2_555 N
Mn1 Li1 O2 47.760(7) -1_565 . -1_565 N
Mn1 Li1 O2 47.760(7) -1_565 . -2_565 N
O1 Li1 O1 180.0 101_455 . 102_555 N
O1 Li1 O2 103.099(12) 101_455 . 1_555 N
O1 Li1 O2 76.901(12) 101_455 . 2_555 N
O1 Li1 O2 76.901(12) 101_455 . -1_565 N
O1 Li1 O2 103.099(12) 101_455 . -2_565 N
O1 Li1 O2 76.901(12) 102_555 . 1_555 N
O1 Li1 O2 103.099(12) 102_555 . 2_555 N
O1 Li1 O2 103.099(12) 102_555 . -1_565 N
O1 Li1 O2 76.901(12) 102_555 . -2_565 N
O2 Li1 O2 95.521(15) 1_555 . 2_555 N
O2 Li1 O2 179.9802 1_555 . -1_565 N
O2 Li1 O2 84.479(15) 1_555 . -2_565 N
O2 Li1 O2 84.479(15) 2_555 . -1_565 N
O2 Li1 O2 179.9802 2_555 . -2_565 N
O2 Li1 O2 95.521(15) -1_565 . -2_565 N
Mn1 O1 Mn1 99.822(15) 1_555 . -1_555 N
Mn1 O1 Li1 99.497(11) 1_555 . 101_545 N
Mn1 O1 Mn2 99.497(11) 1_555 . 101_545 N
Mn1 O1 Li1 99.497(11) -1_555 . 101_545 N
Mn1 O1 Mn2 99.497(11) -1_555 . 101_545 N
Li1 O1 Mn2 0.0 101_545 . 101_545 N
Mn1 O2 Mn1 94.813(13) 1_555 . -101_445 N
Mn1 O2 Li1 83.851(15) 1_555 . 1_555 N
Mn1 O2 Mn2 83.851(15) 1_555 . 1_555 N
Mn1 O2 Mn3 87.134(14) 1_555 . -1_565 N
Mn1 O2 Li1 99.139(13) -101_445 . 1_555 N
Mn1 O2 Mn2 99.139(13) -101_555 . 1_555 N
Mn1 O2 Mn3 131.267(11) -101_555 . -1_565 N
Li1 O2 Mn2 0.0 1_555 . 1_555 N
Li1 O2 Mn3 129.379(12) 1_555 . -1_565 N
Mn2 O2 Mn3 129.379(12) 1_555 . -1_565 N
O1 Mn2 O1 180.0 101_455 . 102_555 N
O1 Mn2 O2 103.099(12) 101_455 . 1_555 N
O1 Mn2 O2 76.901(12) 101_455 . 2_555 N
O1 Mn2 O2 76.901(12) 101_455 . -1_565 N
O1 Mn2 O2 103.099(12) 101_455 . -2_565 N
O1 Mn2 O2 76.901(12) 102_555 . 1_555 N
O1 Mn2 O2 103.099(12) 102_555 . 2_555 N
O1 Mn2 O2 103.099(12) 102_555 . -1_565 N
O1 Mn2 O2 76.901(12) 102_555 . -2_565 N
O2 Mn2 O2 95.521(15) 1_555 . 2_555 N
O2 Mn2 O2 179.9802 1_555 . -1_565 N
O2 Mn2 O2 84.479(15) 1_555 . -2_565 N
O2 Mn2 O2 84.479(15) 2_555 . -1_565 N
O2 Mn2 O2 179.9802 2_555 . -2_565 N
O2 Mn2 O2 95.521(15) -1_565 . -2_565 N
Mn1 Mn3 Mn1 151.654(7) -1_565 . -1_566 N
Mn1 Mn3 O2 56.188(12) -1_565 . -1_565 N
Mn1 Mn3 O2 143.933(8) -1_565 . -2_566 N
Mn1 Mn3 Mn3 108.935(15) -1_565 . -101_466 N
Mn1 Mn3 Mn3 71.764(15) -1_565 . -101_566 N
Mn1 Mn3 O2 143.933(8) -1_566 . -1_565 N
Mn1 Mn3 O2 56.188(12) -1_566 . -2_566 N
Mn1 Mn3 Mn3 71.764(15) -1_566 . -101_466 N
Mn1 Mn3 Mn3 108.935(15) -1_566 . -101_566 N
O2 Mn3 O2 118.095(15) -1_565 . -2_566 N
O2 Mn3 Mn3 75.912(14) -1_565 . -101_466 N
O2 Mn3 Mn3 102.657(14) -1_565 . -101_566 N
O2 Mn3 Mn3 102.657(14) -2_566 . -101_466 N
O2 Mn3 Mn3 75.912(14) -2_566 . -101_566 N
Mn3 Mn3 Mn3 177.2927(8) -101_466 . -101_566 N
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_1
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Mn1 Mn1 2.8397(5) . -101_345 N
Mn1 Mn1 2.8397(5) . -101_445 N
Mn1 Li1 2.8258(6) . 1_555 N
Mn1 Li1 2.9516(5) . 101_445 N
Mn1 Li1 2.9516(5) . 101_545 N
Mn1 O1 1.99662(27) . 1_555 N
Mn1 O1 1.99662(27) . 2_555 N
Mn1 O2 2.10412(27) . 1_555 N
Mn1 O2 2.10412(27) . 2_555 N
Mn1 O2 1.7386(4) . -101_445 N
Mn1 O2 1.7386(4) . -102_345 N
Mn1 Mn2 2.8258(6) . 1_555 N
Mn1 Mn2 2.9516(5) . 101_445 N
Mn1 Mn2 2.9516(5) . 101_545 N
Mn1 Mn3 2.5293(4) . -1_565 N
Mn1 Mn3 2.5293(4) . -1_566 N
Mn1 Mn3 2.9632(7) . 101_444 N
Mn1 Mn3 2.9632(7) . 101_545 N
Li1 Mn1 2.8258(6) . 1_555 N
Li1 Mn1 2.8258(6) . -1_565 N
Li1 Mn1 2.9516(5) . 101_455 N
Li1 Mn1 2.9516(5) . 101_555 N
Li1 Mn1 2.9516(5) . -101_345 N
Li1 Mn1 2.9516(5) . -101_445 N
Li1 O1 1.8692(5) . 101_455 N
Li1 O1 1.8692(5) . 102_555 N
Li1 O2 2.12495(28) . 1_555 N
Li1 O2 2.12495(28) . 2_555 N
Li1 O2 2.12495(28) . -1_565 N
Li1 O2 2.12495(28) . -2_565 N
O1 Mn1 1.99662(27) . 1_555 N
O1 Mn1 1.99662(27) . -1_555 N
O1 Li1 1.8692(5) . 101_545 N
O1 Mn2 1.8692(5) . 101_545 N
O1 Mn3 2.5625(4) . 1_544 N
O1 Mn3 2.5625(4) . -1_565 N
O2 Mn1 2.10412(27) . 1_555 N
O2 Mn1 1.7386(4) . -101_445 N
O2 Li1 2.12495(28) . 1_555 N
O2 Mn2 2.12495(28) . 1_555 N
O2 Mn3 1.51266(26) . -1_565 N
Mn2 Mn1 2.8258(6) . 1_555 N
Mn2 Mn1 2.8258(6) . -1_565 N
Mn2 Mn1 2.9516(5) . 101_455 N
Mn2 Mn1 2.9516(5) . 101_555 N
Mn2 Mn1 2.9516(5) . -101_345 N
Mn2 Mn1 2.9516(5) . -101_445 N
Mn2 O1 1.8692(5) . 101_455 N
Mn2 O1 1.8692(5) . 102_555 N
Mn2 O2 2.12495(28) . 1_555 N
Mn2 O2 2.12495(28) . 2_555 N
Mn2 O2 2.12495(28) . -1_565 N
Mn2 O2 2.12495(28) . -2_565 N
Mn3 Mn1 2.5293(4) . -1_565 N
Mn3 Mn1 2.5293(4) . -1_566 N
Mn3 Mn1 2.9632(7) . 101_455 N
Mn3 Mn1 2.9632(7) . 101_556 N
Mn3 O1 2.5625(4) . 1_566 N
Mn3 O1 2.5625(4) . 2_565 N
Mn3 O2 1.51266(26) . -1_565 N
Mn3 O2 1.51266(26) . -2_566 N
Mn3 Mn3 2.5263(6) . -101_356 N
Mn3 Mn3 2.5263(6) . -101_456 N
loop_
_pd_meas_counts_total
_pd_proc_ls_weight
_pd_proc_intensity_bkg_calc
_pd_calc_intensity_total
451.0 0.0 210.31895 .
464.0 0.0 210.69101 .
449.0 0.0 211.06097 .
415.0 0.0 211.42905 .
436.0 0.0 211.79507 .
469.0 0.0 212.15919 .
445.0 0.0 212.52133 .
453.0 0.0 212.88152 .
450.0 0.0 213.23973 .
464.0 0.0 213.59596 .
436.0 0.0 213.95029 .
460.0 0.0 214.30264 .
438.0 0.0 214.65309 .
448.0 0.0 215.00160 .
455.0 0.0 215.34814 .
448.0 0.0 215.69278 .
443.0 0.0 216.03552 .
443.0 0.0 216.37637 .
436.0 0.0 216.71526 .
427.0 0.0 217.05222 .
437.0 0.0 217.38733 .
412.0 0.0 217.72054 .
420.0 0.0 218.05180 .
400.0 0.0 218.38121 .
434.0 0.0 218.70871 .
390.0 0.0 219.03433 .
429.0 0.0 219.35809 .
459.0 0.0 219.67996 .
436.0 0.0 219.99998 .
443.0 0.0 220.31816 .
449.0 0.0 220.63446 .
449.0 0.0 220.94891 .
429.0 0.0 221.26151 .
432.0 0.0 221.57217 .
419.0 0.0 221.88107 .
423.0 0.0 222.18816 .
410.0 0.0 222.49336 .
426.0 0.0 222.79675 .
439.0 0.0 223.09834 .
440.0 0.0 223.39809 .
391.0 0.0 223.69603 .
410.0 0.0 223.99210 .
390.0 0.0 224.28641 .
413.0 0.0 224.57889 .
442.0 0.0 224.86960 .
397.0 0.0 225.15851 .
432.0 0.0 225.44560 .
440.0 0.0 225.73094 .
403.0 0.0 226.01448 .
400.0 0.0 226.29623 .
390.0 0.0 226.57620 .
447.0 0.0 226.85443 .
408.0 0.0 227.13086 .
423.0 0.0 227.40559 .
383.0 0.0 227.67848 .
389.0 0.0 227.94968 .
371.0 0.0 228.21907 .
389.0 0.0 228.48677 .
416.0 0.0 228.75273 .
372.0 0.0 229.01689 .
407.0 0.0 229.27933 .
393.0 0.0 229.54007 .
375.0 0.0 229.79904 .
373.0 0.0 230.05638 .
395.0 0.0 230.31189 .
360.0 0.0 230.56578 .
374.0 0.0 230.81790 .
412.0 0.0 231.06836 .
367.0 0.0 231.31711 .
373.0 0.0 231.56413 .
364.0 0.0 231.80949 .
377.0 0.0 232.05316 .
368.0 0.0 232.29514 .
424.0 0.0 232.53543 .
412.0 0.0 232.77406 .
391.0 0.0 233.01103 .
387.0 0.0 233.24631 .
361.0 0.0 233.47993 .
370.0 0.0 233.71187 .
364.0 0.0 233.94215 .
380.0 0.0 234.17081 .
393.0 0.0 234.39783 .
386.0 0.0 234.62317 .
352.0 0.0 234.84689 .
398.0 0.0 235.06894 .
398.0 0.0 235.28943 .
339.0 0.0 235.50827 .
369.0 0.0 235.72543 .
361.0 0.0 235.94104 .
337.0 0.0 236.15497 .
360.0 0.0 236.36729 .
363.0 0.0 236.57808 .
359.0 0.0 236.78719 .
342.0 0.0 236.99474 .
369.0 0.0 237.20068 .
359.0 0.0 237.40503 .
354.0 0.0 237.60777 .
368.0 0.0 237.80894 .
373.0 0.0 238.00851 .
365.0 0.0 238.20659 .
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71.0 0.01408 70.75863 87.48502
78.0 0.01282 70.76420 87.19695
65.0 0.01538 70.77005 86.91431
81.0 0.01235 70.77619 86.63710
71.0 0.01408 70.78264 86.36539
72.0 0.01389 70.78938 86.09926
76.0 0.01316 70.79642 85.83885
74.0 0.01351 70.80376 85.58421
68.0 0.01471 70.81142 85.33555
75.0 0.01333 70.81937 85.09290
71.0 0.01408 70.82762 84.85635
58.0 0.01724 70.83618 84.62621
63.0 0.01587 70.84505 84.40243
84.0 0.01190 70.85423 84.18510
74.0 0.01351 70.86373 83.97434
59.0 0.01695 70.87354 83.77010
98.0 0.01020 70.88366 83.56048
66.0 0.01515 70.89410 83.36958
73.0 0.01370 70.90485 83.18526
77.0 0.01299 70.91594 83.00753
51.0 0.01961 70.92734 82.83637
82.0 0.01220 70.93906 82.67168
69.0 . . .
